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Novel planar chiral P,N-[2.2]paracyclophane ligands: synthesis and application in palladium-catalyzed allylic alkylation

✍ Scribed by Xun-Wei Wu; Ke Yuan; Wei Sun; Ming-Jie Zhang; Xue-Long Hou

Book ID: 104359583
Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 251 KB
Volume: 14
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(02)00790-5

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✦ Synopsis

A series of planar chiral P,N-[2.2]paracyclophane ligands were synthesized and applied in enantioselective palladiumcatalyzed allylic alkylation, in which the central chirality of [2.2]paracyclophane is the dominant stereocontrol element. The effect of the substituents attached to the phosphorus atom of these ligands on the yield and stereoselectivity of the reaction was also investigated.

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