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Synthesis of new planar chiral [2.2]paracyclophane Schiff base ligands and their application in the asymmetric Henry reaction

✍ Scribed by Dongyue Xin; Yudao Ma; Fuyan He


Book ID
108284547
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
929 KB
Volume
21
Category
Article
ISSN
0957-4166

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πŸ“œ SIMILAR VOLUMES


Novel chiral tridentate Schiff base liga
✍ Tatyana I. Danilova; Valeria I. Rozenberg; Elena V. Sergeeva; Zoya A. Starikova; πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 268 KB

The first example of the efficient application of chiral tridentate N,O-[2.2]paracyclophane ligands of the imino type for enantioselective diethylzinc addition to aliphatic and aromatic aldehydes is presented. The enantiomeric excess of the resulted secondary alcohols is up to 93% e.e.