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Synthesis of planar chiral [2.2]paracyclophane Schiff bases for the enantioselective Henry reaction

โœ Scribed by Fuyan He; Yudao Ma; Lei Zhao; Wenzeng Duan; Jianqiang Chen; Zhongxi Zhao


Book ID
116909666
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
807 KB
Volume
23
Category
Article
ISSN
0957-4166

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๐Ÿ“œ SIMILAR VOLUMES


Novel chiral tridentate Schiff base liga
โœ Tatyana I. Danilova; Valeria I. Rozenberg; Elena V. Sergeeva; Zoya A. Starikova; ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 268 KB

The first example of the efficient application of chiral tridentate N,O-[2.2]paracyclophane ligands of the imino type for enantioselective diethylzinc addition to aliphatic and aromatic aldehydes is presented. The enantiomeric excess of the resulted secondary alcohols is up to 93% e.e.