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Synthesis of phosphopeptides via global phosphorylation on the solid phase: Resolution of H-phosphonate formation

โœ Scribed by John W. Perich

Book ID
105576486
Publisher
Springer Netherlands
Year
1998
Tongue
English
Weight
529 KB
Volume
5
Category
Article
ISSN
1573-3149

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๐Ÿ“œ SIMILAR VOLUMES

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The seven phosphopeptide derivatives based on the native -NEYTA- sequence of the pp60src protein kinase family, Asn-Glu-Tyr(P)-Ser-Ala, Ala-Glu-Tyr(P)-Ser-Ala, Ala-Ser-Tyr(P)-Ser-Ala, Ala-Ser(P)-Tyr-Ser-Ala, Ala-Thr-Tyr(P)-Ser-Ala, Ala-Thr(P)-Tyr-Ser-Ala and Ala-Ser(P)-Tyr(P)-Ser-Ala, were prepared

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A novel method for the efficient synthesis of Tyr(P)-containing peptides is described by the 'phosphite-triester' phosphorylation of the tyrosine residue after its incorporation into the peptide chain. In this approach, the peptide resin is assembled by Fmoc solid-phase peptide synthesis (PyBOP ยฎ co