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Synthesis of perhydroisoquinoline derivatives mediated by (η6-arene)Cr(CO)3 complexes

✍ Scribed by Ming-Chang P. Yeh; Chong-Nan Chuang; Chun-Hsiang Yiu

Book ID
104258040
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
193 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reaction of lithium hexamethyldisilazide (LHMDS) with Cq6-arene)Cr(CO)3 complexes bearing a ~-alaninenitrile moiety gives tetrahydroisoquinoline derivatives as the major products after oxidation of the reaction intermediate, whereas protonation of the reaction intermediates produces hexahydroisoquinoline as the major products.

📜 SIMILAR VOLUMES

Hydrogen bonding networks in [(η6-arene)
Hydrogen bonding networks in [(η6-arene)Cr(CO)3] complexes
✍ Balasubramanian Murugesapandian; Peter W. Roesky 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 293 KB 👁 1 views

The four different [(η 6 -arene) and [{η 6 -(1,4-C 6 H 4 (NH 2 )CH 3 )}Cr(CO) 3 ] were synthesized and structurally characterized by single crystal X-ray diffraction. All compounds form hydrogen bonds in the solid state, leading to dimeric or polymeric networks. The hydrogen bonds are an essential