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Stereoselective synthesis of key (η6-arene)Cr(CO)3 complexes to acorenone and acorenone B

✍ Scribed by Motokazu Uemura; Toshio Kobayashi; Tatsuya Minami; Yuji Hayashi

Book ID
104218643
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
210 KB
Volume
27
Category
Article
ISSN
0040-4039

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Synthesis of perhydroisoquinoline deriva
Synthesis of perhydroisoquinoline derivatives mediated by (η6-arene)Cr(CO)3 complexes
✍ Ming-Chang P. Yeh; Chong-Nan Chuang; Chun-Hsiang Yiu 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 193 KB

Reaction of lithium hexamethyldisilazide (LHMDS) with Cq6-arene)Cr(CO)3 complexes bearing a ~-alaninenitrile moiety gives tetrahydroisoquinoline derivatives as the major products after oxidation of the reaction intermediate, whereas protonation of the reaction intermediates produces hexahydroisoquin