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Synthesis of Pederic Acid and Related Model Studies.

✍ Scribed by Steffen Breitfelder; Anne C. Schuemacher; Thomas Roelle; Makoto Kikuchi; Reinhard W. Hoffmann

Book ID
101967672
Publisher
John Wiley and Sons
Year
2004
Weight
9 KB
Volume
35
Category
Article
ISSN
0931-7597

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Synthesis of Pederic Acid and Related Mo
Synthesis of Pederic Acid and Related Model Studies
✍ Steffen Breitfelder; Anneβ€…C. Schuemacher; Thomas RΓΆlle; Makoto Kikuchi; Reinhard πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 German βš– 208 KB

## Abstract {[2‐(Trimethylsilyl)ethoxy]methyl} (SEM)‐protected pederic acid **16** was prepared by deriving the stereogenic center at C(7) from mannitol and those at C(2) and C(3) (mycalamide numbering) from __trans__‐2,3‐dimethyloxirane. Routes to pederamides involving a late oxygenation at C(7) w