Polymerization of 2-methyl-2-oxazoline was carried out using a trifunctional initiator, 2-perbromomethyl-2-oxazoline. The degree of polymerization (DP) of the resulting polymer was very close to the feed mole ratio of the monomer to initiator. The number-average molecular weight a, increased linearl
Synthesis of palladium clusters with surface initiator for polymerization of 2-methyl-2-oxazoline
β Scribed by Hideaki Itoh; Kensuke Naka; Yoshiki Chujo
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 85 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0170-0839
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The copolymerization of 2-methyl-2-oxazoline, as nucleophilic monomer, and fl-methylhydrogen itaconate (MHI), as electrophilic monomer, without initiator in solution under various conditions was investigated. Copolymers were characterized by elemental analysis, FT-i.r. and ~H-NMR spectroscopy. The c
## Abstract Kinetic investigations on the cationic ringβopening polymerization of 2βethylβ2βoxazoline were conducted using acetyl chloride, acetyl bromide, and acetyl iodide as initiators. Various polymerization temperatures ranging from 80 to 220βΒ°C were applied under microwave irradiation. The re