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Kinetics and mechanism of cationic polymerization of 5-methyl-2-oxazoline. Concurrent propagation through ionic and covalent species with methyl iodide initiator

โœ Scribed by Shiro Kobayashi; Kenji Morikawa; Naoki Shimizu; Takeo Saegusa

Publisher
Springer
Year
1984
Tongue
English
Weight
335 KB
Volume
11
Category
Article
ISSN
0170-0839

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โœ Andrzej Dworak ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 617 KB

It was shown that in the polymerization of 2-methyl-2-oxazoline initiated with benzyl bromide in nitrobenzene the equilibrium constant of the interconversion of cationic and covalent active centers could be measured over a wide range of temperatures, thus making the thermodynamic parameters of this