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2-Perbromomethyl-2-oxazoline: a novel trifunctional initiator for the ring-opening polymerization of 2-methyl-2-oxazoline

✍ Scribed by Tushar Kanti Bera; Swaminathan Sivaram

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
348 KB
Volume
196
Category
Article
ISSN
1022-1352

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✦ Synopsis

Polymerization of 2-methyl-2-oxazoline was carried out using a trifunctional initiator, 2-perbromomethyl-2-oxazoline. The degree of polymerization (DP) of the resulting polymer was very close to the feed mole ratio of the monomer to initiator. The number-average molecular weight a, increased linearly with conversion, indicating the living nature of the propagating chain end. 'H NMR and end-group analyses results are consistent with the proposal that the polymer possesses a star-shaped structure.

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