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Synthesis of novel chiral oxazoline ligands and application in the highly enantioselective diethylzinc addition to N-diphenylphosphinoylimines

โœ Scribed by Gexin Yan; Yong Wu; Wenqing Lin; Xiaomei Zhang


Book ID
108284283
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
175 KB
Volume
18
Category
Article
ISSN
0957-4166

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๐Ÿ“œ SIMILAR VOLUMES


The first use of chiral oxazoline ligand
โœ Xiaomei Zhang; Wenqing Lin; Liuzhu Gong; Aiqiao Mi; Xin Cui; Yaozhong Jiang; Mic ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 62 KB

A series of chiral oxazolines, which had been conveniently prepared from commercially available (1S,2S)-2-amino-1phenylpropane-1,3-diol, was applied in the diethylzinc addition to diphenylphosphinoyl imines to give high yields of 68-84% and excellent e.e. values of 90-93%.