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Synthesis of novel 2,5-dihydro-1,5,2-diazaphosphinines from primary enamine phosphonates and from alkyl phosphonates

✍ Scribed by Francisco Palacios; Ana M. Ochoa de Retana; Sergio Pascual; Rafael López de Munain; Julen Oyarzabal; José M. Ezpeleta


Book ID
108282842
Publisher
Elsevier Science
Year
2005
Tongue
French
Weight
292 KB
Volume
61
Category
Article
ISSN
0040-4020

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A simple route to novel 2,5-dihydro-1,5,
✍ Francisco Palacios; Ana M Ochoa de Retana; Sergio Pascual; Rafael López de Munai 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 83 KB

A simple method for the preparation of phosphorus-containing pyrimidine analogues such as 4,6-disubstituted-2ethoxy-2,5-dihydro-1,5,2-diazaphosphinine 2-oxides 5 from primary enamine phosphonates and nitriles is described. A similar strategy is used for the synthesis of the corresponding 4,6-difluor