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Synthesis of new mono-N-tosylated diamine ligands based on (R)-(+)-limonene and their application in asymmetric transfer hydrogenation of ketones and imines

✍ Scribed by Roszkowski, Piotr; Maurin, Jan K.; Czarnocki, Zbigniew


Book ID
120378385
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
906 KB
Volume
24
Category
Article
ISSN
0957-4166

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Synthesis of novel chiral Schiff bases a
✍ Zhongqiang Zhou; Yongjun Bian πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 100 KB

## Abstract Novel chiral Schiff bases were synthesized from (+)‐camphor, and their application to asymmetric transfer hydrogenation of prochiral ketones is described. The asymmetric transfer hydrogenation reaction could afford excellent conversion rates (up to 97.3%) and up to 27.3% enantiomeric ex