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Water-soluble arene ruthenium catalysts containing sulfonated diamine ligands for asymmetric transfer hydrogenation of ?-aryl ketones and imines in aqueous solution

✍ Scribed by Canivet, J?r?me; S?ss-Fink, Georg

Book ID
111895198
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
404 KB
Volume
9
Category
Article
ISSN
1463-9262

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Water-Soluble Arene Ruthenium Complexes
Water-Soluble Arene Ruthenium Complexes Containing a trans-1,2-Diaminocyclohexane Ligand as Enantioselective Transfer Hydrogenation Catalysts in Aqueous Solution
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## Abstract The cationic chloro complexes [(arene)Ru(H~2~N∩NH~2~)Cl]^+^ (1: arene = C~6~H~6~; 2: arene = __p__‐MeC~6~H~4~__i__Pr; 3: arene = C~6~Me~6~) have been synthesised from the corresponding arene ruthenium dichloride dimers and enantiopure (__R__,__R__ or __S__,__S__) __trans__‐1,2‐diaminocy

Water-Soluble Arene Ruthenium Complexes
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## Abstract **The cover picture shows** the postulated catalytic cycle for the pH‐dependent, enantioselective transfer hydrogenation of acetophenone to give phenylethanol in water, using formate as hydrogen donor and (arene)ruthenium(__trans__‐diaminocyclohexane) as chiral catalyst. This work illus