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Synthesis of new functional acenaphthylene derivatives. 2. Regioselective electrophilic substitution of silylated acenaphthenes and acenaphthylenes

✍ Scribed by Felix, Guy; Laguerre, Michel; Dunogues, Jacques; Calas, Raymond


Book ID
121333772
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
608 KB
Volume
47
Category
Article
ISSN
0022-3263

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Synthesis of new acenaphthylene function
✍ Laguerre, Michel; Felix, Guy; Dunogues, Jacques; Calas, Raymond πŸ“‚ Article πŸ“… 1979 πŸ› American Chemical Society 🌐 English βš– 531 KB

0.75 g, 15 mmol) and chlorotrimethylsilane (3.15 mL, 25 mmol) in dry acetonitrile (25 mL). The progress of the reactions was monitored by IR, and they were complete in 6-8 h. Pure silyl nitronates were obtained after workup and characterized by their NMR and IR spectra. Silyl nitronate of 6a: 1.0 g