Synthesis of Natural Products By Rhodium-Mediated Intramolecular C–H Insertion
✍ Scribed by Douglass F. Taber; Salah-E. Stiriba
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 74 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0947-6539
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✦ Synopsis
Rh-mediated intramolecular C ± H insertion allows the direct construction of carbon ± carbon bonds at previously unactivated centers. The natural product syntheses described here highlight the strategic advantages and efficiencies this reaction offers.
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Rhodium has proven to be an extremely useful metal due to its ability to catalyze an array of synthetic transformations, with quite often-unique selectivity. Hydrogenation, C-H activation, allylic substitution, and numerous other reactions are catalyzed by this metal, which presumably accounts for t
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