Rhodium has proven to be an extremely useful metal due to its ability to catalyze an array of synthetic transformations, with quite often-unique selectivity. Hydrogenation, C-H activation, allylic substitution, and numerous other reactions are catalyzed by this metal, which presumably accounts for t
Cyclopentane Construction by Rhodium(II)-Mediated Intramolecular C—H Insertion
✍ Scribed by Douglass F. Taber; Pramod V. Joshi
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
Rh-mediated intramolecular C ± H insertion allows the direct construction of carbon ± carbon bonds at previously unactivated centers. The natural product syntheses described here highlight the strategic advantages and efficiencies this reaction offers.
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