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Synthesis of N-Methylmorpholinium 1-Amino-2,4-dicyano-4-phenylcarbamoyl (ethoxycarbonyl)-1,3-butadiene-1-thiolates and Their Transformation into Pyridine-2-thiol Derivatives.

โœ Scribed by V. D. Dyachenko; R. P. Tkachev


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
33
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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ChemInform Abstract: Synthesis of N-Meth
โœ V. D. DYACHENKO; V. P. LITVINOV ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 1 views

Synthesis of N-Methylmorpholinium 6-Amino-4-aryl-4-methyl-3,5dicyano-1,4-dihydropyridine-2-thiolates under Conditions of Michael Reaction. -Reaction of alkylidenemalononitriles (I) with cyanothioacetamide (II) affords the corresponding Michael adducts which cyclize immediately to the title 1,4-dihy