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4,4-Dialkyl-Substituted N-Methylmorpholinium 3,5-Dicyano-6-oxo-1,4,5,6-tetrahydropyridine-2-thiolates and Some of Their Properties.

โœ Scribed by V. D. Dyachenko; A. A. Nikishin; A. N. Chernega


Publisher
John Wiley and Sons
Year
2004
Weight
132 KB
Volume
35
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Ethylcrotonates in
โœ V. D. DYACHENKO; A. A. NIKISHIN; V. P. LITVINOV ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 2 views

Ethylcrotonates in the Synthesis of 4,4-Disubstituted 3,5-Dicyano-6oxo-1,4,5,6-tetrahydropyridine-2-thiolates. -Michael addition of ethyl crotonate (I) to cyanothioacetamide (II) in the presence of N-methylmorpholine and subsequent in situ cyclization affords the title tetrahydropyridinethiolates as