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ChemInform Abstract: Synthesis, Alkylation, Molecular and Crystal Structure of N- Methylmorpholinium 6-Amino-3,5-dicyano-1,4-dihydropyridinespiro-4- cyclohexane-2-thiolate (IV).

โœ Scribed by V. D. DYACHENKO; S. G. KRIVOKOLYSKO; V. N. NESTEROV; YU. T. STRUCHKOV; V. P. LITVINOV

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of N-Methylmorpholinium 6-Amino-4-aryl-4-methyl-3,5-dicyano-1,4-dihydropyridine-2-thiolates under Conditions of Michael Reaction.
โœ V. D. DYACHENKO; V. P. LITVINOV ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 1 views

Synthesis of N-Methylmorpholinium 6-Amino-4-aryl-4-methyl-3,5dicyano-1,4-dihydropyridine-2-thiolates under Conditions of Michael Reaction. -Reaction of alkylidenemalononitriles (I) with cyanothioacetamide (II) affords the corresponding Michael adducts which cyclize immediately to the title 1,4-dihy