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Synthesis of N-isobutylamide of 2e,4e-decadienoic acid(pellitorine) from butadiene-acetic acid telomer

โœ Scribed by L. I. Zakharkin; E. A. Petrushkina


Book ID
112447746
Publisher
Springer
Year
1982
Tongue
English
Weight
189 KB
Volume
31
Category
Article
ISSN
1573-9171

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Pellitorine is an insecticidal compound isolated from Anacyckus pyrethrum roots. Its structure was determinded as N-isobutyl-E,E-2,4\_decadieneamide (IVc), which was prepared easily from E,E-2,4-decadienoic acid, 1 and hence the preparation of the acid means the synthesis of pellitorine. Crombie' an

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## Abstract The title compound 4โ€(Nโ€acetylamino) phenylโ€1โ€[^14^C] retinoate (3) was synthesized by a 2โ€step sequence. Carboxylโ€[^14^C] vitamin A (1) was treated with ethylchloroformate to form the mixed anhydride (2). Treatment with acetamidophenol and heating with a catalytical amount of 4โ€dimethy