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Synthesis of Medium-Ring and Iodinated Biaryl Compounds by Organocuprate Oxidation

✍ Scribed by David S. Surry; Xianbin Su; David J. Fox; Vilius Franckevicius; Simon J. F. Macdonald; David R. Spring


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
121 KB
Volume
44
Category
Article
ISSN
0044-8249

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Acceptor-substituted cycloalkenones 1 undergo an iron(III)catalyzed vinylogous Michael reactiona sequence of enone-dienol tautomerism, [4+2]-cycloaddition, and retro-aldol reactionwith quinone derivatives 3. A variety of products is obtained ranging from meta-terphenyl precursors 5 to