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Synthesis of magnesium catecholate ando-semiquinone complexes by oxidation of the metal with 3,6-di-tert-butyl-o-benzoquinone

✍ Scribed by A. V. Piskunov; A. V. Lado; G. A. Abakumov; V. K. Cherkasov; O. V. Kuznetsova; G. K. Fukin; E. V. Baranov


Book ID
106520360
Publisher
Springer
Year
2007
Tongue
English
Weight
387 KB
Volume
56
Category
Article
ISSN
1573-9171

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## Abstract The reduction of 3,6‐di‐__tert__‐butyl‐__o__‐benzoquinone with tin amalgam gives the different tin catecholate complexes. The use of polar solvents for this reaction leads to the formation of Cat~2~Sn · L~2~ species (where Catβ€”dianion of 3,6‐di‐__tert__‐butylcatechol, L = Et~2~O, THF, P