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Synthesis of heterocyclic derivatives of 3,6-di-tert-butyl-o-benzoquinone by catalytic dehydrocondensation with ethylene glycol, glycerol, and diethanolamine

✍ Scribed by T. I. Prokof'eva; V. B. Vol'eva; A. I. Prokof'ev; S. Belostotskaya; N. L. Komissarov; V. V. Ershov


Book ID
105516720
Publisher
Springer US
Year
2000
Tongue
English
Weight
296 KB
Volume
36
Category
Article
ISSN
0009-3122

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The Reaction of 3,6-di-tert-butyl-o-benz
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## Abstract The reduction of 3,6‐di‐__tert__‐butyl‐__o__‐benzoquinone with tin amalgam gives the different tin catecholate complexes. The use of polar solvents for this reaction leads to the formation of Cat~2~Sn · L~2~ species (where Catβ€”dianion of 3,6‐di‐__tert__‐butylcatechol, L = Et~2~O, THF, P