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Reaction of 3,6-di-tert-butyl-o-benzoquinone with dimedone. Functionalized derivatives of hinderedo-quinones and catechols

โœ Scribed by G. A. Abakumov; V. I. Nevodchikov; N. V. Zaitova; N. O. Druzhkov; L. G. Abakumova; Yu. A. Kurskii; V. K. Cherkasov


Publisher
Springer
Year
1997
Tongue
English
Weight
287 KB
Volume
46
Category
Article
ISSN
1573-9171

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The Reactions of 3,6-Di-tert-butyl-1,2-benzoquinone and 3,6-Ditert-butylcatechol with tert-Butyl Hydroperoxide. -The reaction of the title quinone (I) as well as its corresponding catechol with tert-butyl hydroperoxide in aprotic solvents results in ring oxidation accompanied by ring expansion furn