Stereochemical features of the paramagnetic complex formed by the reaction of 3,6-di-tert-butyl-o-benzoquinone with tetrachlorostannane
β Scribed by A. I. Prokof'ev; Z. K. Kasymbekova; N. N. Budnov; S. P. Solodovnikov; M. I. Kabachnik
- Book ID
- 112446128
- Publisher
- Springer
- Year
- 1982
- Tongue
- English
- Weight
- 508 KB
- Volume
- 31
- Category
- Article
- ISSN
- 1573-9171
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The Reactions of 3,6-Di-tert-butyl-1,2-benzoquinone and 3,6-Ditert-butylcatechol with tert-Butyl Hydroperoxide. -The reaction of the title quinone (I) as well as its corresponding catechol with tert-butyl hydroperoxide in aprotic solvents results in ring oxidation accompanied by ring expansion furn
## Abstract The reduction of 3,6βdiβ__tert__βbutylβ__o__βbenzoquinone with tin amalgam gives the different tin catecholate complexes. The use of polar solvents for this reaction leads to the formation of Cat~2~SnβΒ·βL~2~ species (where Catβdianion of 3,6βdiβ__tert__βbutylcatechol, L = Et~2~O, THF, P