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Synthesis of Indolines, Indoles, and Benzopyrrolizidinones from Simple Aryl Azides

✍ Scribed by Brucelle, François; Renaud, Philippe

Book ID
111873423
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
548 KB
Volume
14
Category
Article
ISSN
1523-7060

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## Abstract Indoline‐2‐thiones **1a‐b,d,f,h**, which have at least one hydrogen at the 3‐position reacted with α‐halo ester **2a‐d**, α‐halo ketones **2e‐f**, and a‐bromoacetonitrile **2g** to give 2‐alkylthioindole derivatives **3–11**. In a similar manner treatment of 3,3‐disubstituted indoline‐2