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Synthesis of natural products via tertiary azides. II. 2-alkyl and 2-aryl indoles.

✍ Scribed by Gérard Adam; Jean Andriblix; Michel Plat

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
202 KB
Volume
22
Category
Article
ISSN
0040-4039

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## Jersey 07065 A new general synthesis leading to 24kyl and 2-aryl-l-carba-2-penem-3-carboxylic acids involves the preparation of a key thiolester intermediate 3. This is reacted with Me CuLi or (C6H5)2MgCuX to give the correspond@ methyl or phenyl ketone which undergoes a Wittig rea A\* mn to gi