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Synthesis of hexahydro 1,3,5-triCarbalkoxy-s-triazines, octahydro-1,3,5,7-tetracarbalkoxy tetrazocines and their interconvertibility

โœ Scribed by B. S. Thyagarajan; K. C. Majumdar


Book ID
112123298
Publisher
Journal of Heterocyclic Chemistry
Year
1974
Tongue
English
Weight
364 KB
Volume
11
Category
Article
ISSN
0022-152X

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The \({ }^{14} \mathrm{C}\)-uniformly labeled (UL) explosive, octahydro-1,3,5,7-tetranitro-1,3,5,7tetrazocine (HMX) was synthesized in \(40 \%\) yield by nitrolysis of \({ }^{14} \mathrm{C}\)-labeled hexamethylenetetramine (hexamine) in the presence of boron trifluoride diethyl etherate as catalyst.