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Synthesis of Glycosyl Phosphonates by Michael-Type Addition to 2-Nitroglycals

✍ Scribed by Kandasamy Pachamuthu; Ignacio Figueroa-Perez; Ibrahim A. I. Ali; Richard R. Schmidt

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 84 KB
Volume: 2004
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200400266

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✦ Synopsis

Abstract

A new synthetic strategy, which allows to synthesize both α‐ and β‐anomers of 2‐acetylaminoglycosyl phosphonate or exclusively β‐anomer is described. The present strategy is a successful Michael‐type addition of dimethyl hydrogen phosphonate to 2‐nitroglycals. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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