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Synthesis of C-glycosyl compounds by the addition of glycosyl radicals to olefins

✍ Scribed by Younosuke Araki; Tadatoshi Endo; Masaki Tanji; Jun'ichi Nagasawa; Yoshiharu Ishido

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
274 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

The Bu3SnH -AIBN induced radical additions of 2,3,f+,6-tetra-Oacetyl-D-glucopyranosyl derivatives, bearing c+Br (l), U-1 (5), @OCSSMe (77, and p-SePh (8) groups on the anomeric carbon, with olefins such as dimethyl maleate, methyl vinyl ketone, dimethyl acetylenedicarboxylate, butyl vinyl ether, and N-ethylmaleimide were examined for a synthesis of C-glycosyl compounds.

📜 SIMILAR VOLUMES

Synthesis of Glycosyl Phosphonates by Mi
Synthesis of Glycosyl Phosphonates by Michael-Type Addition to 2-Nitroglycals
✍ Kandasamy Pachamuthu; Ignacio Figueroa-Perez; Ibrahim A. I. Ali; Richard R. Schm 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 84 KB

## Abstract A new synthetic strategy, which allows to synthesize both α‐ and β‐anomers of 2‐acetylaminoglycosyl phosphonate or exclusively β‐anomer is described. The present strategy is a successful Michael‐type addition of dimethyl hydrogen phosphonate to 2‐nitroglycals. (© Wiley‐VCH Verlag GmbH &