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Synthesis of gem-Difluorinated Cyclopropanes and Cyclopropenes: Trifluoromethyltrimethylsilane as a Difluorocarbene Source

✍ Scribed by Fei Wang; Tao Luo; Prof. Dr. Jinbo Hu; Dr. Ying Wang; Hema S. Krishnan; Dr. Parag V. Jog; Dr. Somesh K. Ganesh; Prof. Dr. G. K. Surya Prakash; Prof. Dr. George A. Olah


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
312 KB
Volume
50
Category
Article
ISSN
0044-8249

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ChemInform Abstract: Synthesis of gem-Di
✍ Fei Wang; Tao Luo; Jinbo Hu; Ying Wang; Hema S. Krishnan; Parag V. Jog; Somesh K 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 35 KB

## Abstract The Ruppert—Prakash reagent Me~3~Si—CF~3~ is an efficient source of difluorocarbene which is generated by sodium iodide or tetrabutylammonium difluorotriphenylsilicate as the initiator.