✦ LIBER ✦

ChemInform Abstract: Synthesis of gem-Difluorinated Cyclopropanes and Cyclopropenes: Trifluoromethyltrimethylsilane as a Difluorocarbene Source.

✍ Scribed by Fei Wang; Tao Luo; Jinbo Hu; Ying Wang; Hema S. Krishnan; Parag V. Jog; Somesh K. Ganesh; G. K. Surya Prakash; George A. Olah

Publisher: John Wiley and Sons
Year: 2011
Weight: 35 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201150037

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The Ruppert—Prakash reagent Me~3~Si—CF~3~ is an efficient source of difluorocarbene which is generated by sodium iodide or tetrabutylammonium difluorotriphenylsilicate as the initiator.

📜 SIMILAR VOLUMES

Synthesis of gem-Difluorinated Cycloprop

Synthesis of gem-Difluorinated Cyclopropanes and Cyclopropenes: Trifluoromethyltrimethylsilane as a Difluorocarbene Source

✍ Fei Wang; Tao Luo; Prof. Dr. Jinbo Hu; Dr. Ying Wang; Hema S. Krishnan; Dr. Para 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 323 KB

Synthesis of gem-Difluorinated Cycloprop

Synthesis of gem-Difluorinated Cyclopropanes and Cyclopropenes: Trifluoromethyltrimethylsilane as a Difluorocarbene Source

✍ Fei Wang; Tao Luo; Prof. Dr. Jinbo Hu; Dr. Ying Wang; Hema S. Krishnan; Dr. Para 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 312 KB

ChemInform Abstract: Chloride Ion-Cataly

ChemInform Abstract: Chloride Ion-Catalyzed Generation of Difluorocarbene for Efficient Preparation of gem-Difluorinated Cyclopropenes and Cyclopropanes.

✍ Fei Wang; Wei Zhang; Jieming Zhu; Huaifeng Li; Kuo-Wei Huang; Jinbo Hu 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 41 KB

ChemInform Abstract: Sodium Bromodifluor

ChemInform Abstract: Sodium Bromodifluoroacetate: A Difluorocarbene Source for the Synthesis of gem-Difluorocyclopropanes.

✍ Kojun Oshiro; Yoshimichi Morimoto; Hideki Amii 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB 👁 1 views

## Abstract Thermolysis of (II) is developed as a novel source of difluorocarbene allowing an effective synthesis of the title compounds.

ChemInform Abstract: Synthesis of gem-Di

ChemInform Abstract: Synthesis of gem-Difluorinated Heterocycles Using a Difluoropropargyl Molecular Scaffold

✍ Satoru Arimitsu; Gerald B. Hammond 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 15 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Synthesis of Difluo

ChemInform Abstract: Synthesis of Difluorinated β-Ketosulfones and Novel gem-Difluoromethylsulfone-Containing Heterocycles as Fluorinated Building Blocks.

✍ Hossein Loghmani-Khouzani; Dariush Hajiheidari 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 27 KB 👁 1 views