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Synthesis of furans by cyclization of 2-En-4-yn-1-ols in the presence of ruthenium and palladium catalysts

✍ Scribed by Bénédicte Seiller; Christian Bruneau; Pierre H. Dixneuf

Book ID
107857681
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
737 KB
Volume
51
Category
Article
ISSN
0040-4020

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Novel synthesis of furan-2-acetic esters
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Furan-2-acetic esters are obtained in good yields by direct oxidative cyclization-alkox~.'carbonylation of (Z)-2-en-4-yn-l-ols. bearing both an alkyl or an aD'l substituent a to the hydrox3' group, in the presence of catalytic amounts of palladium iodide in conjunction with potassium iodide at 50-70

Gold-Catalyzed Cyclization of (Z)-2-En-4
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