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ChemInform Abstract: Synthesis of Furans by Cyclization of 2-En-4-yn-1-ols in the Presence of Ruthenium and Palladium Catalysts.

✍ Scribed by B. SEILLER; C. BRUNEAU; P. H. DIXNEUF

Book ID
112028957
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A General and Facil
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Novel synthesis of furan-2-acetic esters
Novel synthesis of furan-2-acetic esters by palladium-catalysed oxidative cyclization-alkoxycarbonylation of (Z)-2-En-4-yn-1-ols
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Furan-2-acetic esters are obtained in good yields by direct oxidative cyclization-alkox~.'carbonylation of (Z)-2-en-4-yn-l-ols. bearing both an alkyl or an aD'l substituent a to the hydrox3' group, in the presence of catalytic amounts of palladium iodide in conjunction with potassium iodide at 50-70