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Synthesis of Enol Esters and Dimerization of Terminal Alkynes Catalyzed by Neutral and Cationic Vinylidene Ruthenium Complexes.

✍ Scribed by Tom Opstal; Francis Verpoort


Publisher
John Wiley and Sons
Year
2003
Weight
16 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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ChemInform Abstract: Ruthenium-Catalyzed
✍ C. SLUGOVC; K. MEREITER; E. ZOBETZ; R. SCHMID; K. KIRCHNER πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 1 views

Ruthenium-Catalyzed Dimerization of Terminal Alkynes Initiated by a Neutral Vinylidene Complex. -The catalytic coupling of alkynes (III) or (VI) in the presence of Ru complexes such as (I) or (II) leads to butenynes with both conversion and selectivity strongly depending on the alkyne substituent.