𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of Enantiopure α‘-Amino α,β-Epoxy Ketones from α‘-Amino Bromomethyl Ketones

✍ Scribed by Barluenga, José; Baragaña, Beatriz; Concellón, José M.; Piñera-Nicolás, Alejandro; Díaz, M. Rosario; García-Granda, Santiago


Book ID
119954506
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
109 KB
Volume
64
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


α-Chloro-β-amino Ketones
✍ Cromwell, Norman H.; Wankel, Ronald A. 📂 Article 📅 1948 🏛 American Chemical Society 🌐 English ⚖ 345 KB
Synthesis of α-amino ketones
✍ E. Chiorenesku; L. Bukhen-Brylédryanu; R. Shternberg 📂 Article 📅 1961 🏛 Springer 🌐 English ⚖ 301 KB
γ-Amino-β-ketosulfones as chiral educts:
✍ Saumitra Sengupta; Debarati Sen Sarma; Somnath Mondal 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 426 KB

Starting from 'chiral-pool' derived "t-amino-13-ketosulfones, a facile synthesis of enantiopure a-amino ketones has been developed via an ct-alkylation-desulfonation sequence. Extension of this methodology to enantiopure et-acetoxy ketone synthesis,however, have met with limited success.