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γ-Amino-β-ketosulfones as chiral educts: A facile synthesis of enantiopure α-amino ketones

✍ Scribed by Saumitra Sengupta; Debarati Sen Sarma; Somnath Mondal

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
426 KB
Volume
54
Category
Article
ISSN
0040-4020

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✦ Synopsis

Starting from 'chiral-pool' derived "t-amino-13-ketosulfones, a facile synthesis of enantiopure a-amino ketones has been developed via an ct-alkylation-desulfonation sequence. Extension of this methodology to enantiopure et-acetoxy ketone synthesis,however, have met with limited success.

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