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ChemInform Abstract: Synthesis of Enantiopure β- and γ-Amino Alcohols from Homochiral α- and β-Aminoacylsilanes as Stable Synthetic Equivalents of α- and β-Amino Aldehydes.

✍ Scribed by Bianca Flavia Bonini; Mauro Comes-Franchini; Mariafrancesca Fochi; Jacek Gawronski; Germana Mazzanti; Alfredo Ricci; Greta Varchi

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis of Enantiopure β-and γ-Amino Alcohols from Homochiral α-and β-Aminoacylsilanes as Stable Synthetic Equivalents of α-and β-Amino Aldehydes.

-The stereoselectivity is strongly dependent on both the type of protecting group and reagents used. -(BONINI, BIANCA

📜 SIMILAR VOLUMES

Synthesis of Enantiopure β- and γ-Amino
Synthesis of Enantiopure β- and γ-Amino Alcohols from Homochiral α- and β-Aminoacylsilanes as Stable Synthetic Equivalents of α- and β-Amino Aldehydes
✍ Bianca Flavia Bonini; Mauro Comes-Franchini; Mariafrancesca Fochi; Jacek Gawrons 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 206 KB

aminoacylsilanes 1 and 13 and of the N-Ts-aminoacylsilane 5 with allyltrimethylsilane. Lower de values were obtained A practical route is described for the synthesis of enantiopure β-and γ-amino alcohols with two stereocenters, starting from in the Sc(OTf) 3 -catalyzed allylation of 5 with tetraally