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Synthesis of Enantiopure Dehydropiperidinones from α-Amino Acids and Alkynes via Azetidin-3-ones

✍ Scribed by Ishida, Naoki; Yuhki, Tatsuya; Murakami, Masahiro

Book ID
111949836
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
436 KB
Volume
14
Category
Article
ISSN
1523-7060

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✍ Joachim Podlech; Dieter Seebach 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 German ⚖ 673 KB

## Abstract The reactions of azetidin‐3‐ones 6–10, readily available from the amino acids L‐alanine, L‐phenylalanine, L‐valine, L‐lysine, and L‐aspartic acid, __via__ the corresponding diazo ketones, with nucleophilic reagents such as complex hydrides, __Grignard__ compounds, an ester enolate, and