## Abstract For Abstract see ChemInform Abstract in Full Text.
Synthesis of enantiopure 2-acyl azetidines and the application of amino alcohols derived therefrom in enantioselective catalysis
✍ Scribed by François Couty; Damien Prim
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 249 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0957-4166
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📜 SIMILAR VOLUMES
Several novel tri-and tetradentate amino alcohol ligands, all derived from (+)-camphor, have been synthesized by using specific N-alkylation procedures. The amino alcohols were employed as chiral ligands in the nickel catalyzed conjugate additions of diethylzinc to chalcone and cyclohexenone as mode
The C 2 -symmetrical bis-b-amino alcohols 1-6 were prepared and especially attention is focused on bridges, which link the two b-amino alcohol units. These ligands have been applied as chiral catalysts in the asymmetric addition of diethylzinc to aldehydes. sec-Alcohols have been obtained in good yi