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Synthesis of Diverse Macrocyclic Peptidomimetics Utilizing Ring-Closing Metathesis and Solid-Phase Synthesis

✍ Scribed by Barrett, Anthony G. M.; Hennessy, Alan J.; Vézouët, Ronan Le; Procopiou, Panayiotis A.; Seale, Peter W.; Stefaniak, Stefan; Upton, Richard J.; White, Andrew J. P.; Williams, David J.

Book ID
127259343
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
230 KB
Volume
69
Category
Article
ISSN
0022-3263

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Synthesis of macrocyclic lactams and lac
Synthesis of macrocyclic lactams and lactones via ring-closing olefin metathesis
✍ William P.D. Goldring; AndréS. Hodder; Larry Weiler 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 254 KB

## A&Wrack Lactones and lactams 4-6 were synthesized from a series of acyclic dienes 1-3 via ringclosing olefin metathesis, as shown in equation 1. The geometry of the resulting double bond was determined, and the UZratios compared to values from molecular mechanics calculations.