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Synthesis of dinucleoside monophosphorothioates via addition of sulphur to phosphite triesters.

โœ Scribed by Peter M.J. Burgers; Fritz Eckstein

Book ID
104246096
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
201 KB
Volume
19
Category
Article
ISSN
0040-4039

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2-Methylsulfonylethoxy dichlorophosphine has been converted into the mono-N-morpholino derivative and applied for the preparation of 5'-D,N-protected d-nucleoside-3'-phosphoramidites. The latter intermediates could be used in the presence of 1-hydroxyben~otriazole for the formation of 3'-5'-phosphot