Moc; Methoxycarbonyloxy group 3 1) TMSCl, n BuLi 2) BrCH 2 Cl, n BuLi 3 steps, 76% 3) H +
Synthesis of derivatives of oxazolidin-5-ones
✍ Scribed by M. Yu. Katkevich; D. É. Sile; V. A. Slavinska; I. M. Liepinya; Yu. Yu. Popelis
- Book ID
- 104792182
- Publisher
- Springer US
- Year
- 1993
- Tongue
- English
- Weight
- 194 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0009-3122
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📜 SIMILAR VOLUMES
N-carboethoxy-N-alkyl-propargylamines react with iodine, silver tetrafluoroborate and 1-(3-dimethylaminopropyl)-3ethylcarbodiimide hydrochloride to give N-alkyl-S(E)-iodomethylidene-oxazolidin-2-ones which can be converted to the corresponding Salkynylidene-oxazolidin-2-ones by palladium chloride ca
Electrochemically generated tetraethylammonium peroxydicarbonate (IEAPC) and tctraethylammoniunl carbonate (TEAC) react under very mild oanditiuns, with 1,2-amiao alcohols affording, after addition of tosyl chloride, the eorrespending oxazolidin-2-ones in fair to good yields.
A versatile method for the solid phase synthesis of oxazolidin-2-ones is described. A resin bound phenolic group was treated with (±)-epichlorohydrin followed by opening of the epoxide ring with sodium azide. The resulting 1-azido-3-aryloxypropan-2-ol was treated with p-nitrophenylchloroformate and