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Synthesis of crystallizable sydiotactic-atactic stereoblock polypropylene using a living polymerization system

✍ Scribed by Z. Cai; Y. Nakayama; T. Shiono

Book ID: 110170723
Publisher: Springer
Year: 2006
Tongue: English
Weight: 155 KB
Volume: 47
Category: Article
ISSN: 0023-1584
DOI: 10.1134/s0023158406020182

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## Abstract Polymerization of norbornene has been conducted with [__t__‐BuNSiMe~2~(3,6‐__t__‐Bu~2~Flu)]TiMe~2~ (**1**) in toluene at 20 °C using modified methylaluminoxane that contained 0.4 mol‐% of triisobutylaluminium (TIBA) (dMMAO(0.4)) or 1.8 mol‐% of TIBA (dMMAO(1.8)). The **1**‐dMMAO(0.4) ca