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Precise synthesis of olefin block copolymers using a syndiospecific living polymerization system

✍ Scribed by Cai, Zheng-guo; Su, Hai-hui; Shiono, Takeshi


Book ID
121010965
Publisher
Institute of Chemistry Chinese Academy of Sciences
Year
2013
Tongue
English
Weight
309 KB
Volume
31
Category
Article
ISSN
0256-7679

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Catalytic Synthesis of a Monodisperse Ol
✍ Zhengguo Cai; Yuushou Nakayama; Takeshi Shiono πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 121 KB

## Abstract Polymerization of norbornene has been conducted with [__t__‐BuNSiMe~2~(3,6‐__t__‐Bu~2~Flu)]TiMe~2~ (**1**) in toluene at 20 °C using modified methylaluminoxane that contained 0.4 mol‐% of triisobutylaluminium (TIBA) (dMMAO(0.4)) or 1.8 mol‐% of TIBA (dMMAO(1.8)). The **1**‐dMMAO(0.4) ca