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Synthesis of Block Graft Copolymer with Syndiospecific Living Polymerization of Styrene Derivatives by (Trimethyl)pentamethylcyclopentadienyltitanium/Tris(pentafluorophenyl)borane/Trioctylaluminium Catalytic System

✍ Scribed by Masanao Kawabe; Masahide Murata

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 146 KB
Volume: 202
Category: Article
ISSN: 1022-1352
DOI: 10.1002/1521-3935(20010601)202:9<1799::aid-macp1799>3.0.co;2-h

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✦ Synopsis

Transmission electron micrograph of poly{[4MS-b-(S-co-3MS

)]-g-2VP} block graft copolymer.

📜 SIMILAR VOLUMES

Syndiospecific living polymerization of

Syndiospecific living polymerization of 4-methylstyrene with (trimethyl)pentamethylcyclopentadienyltitanium/tris(pentafluorophenyl)borane/trioctylaluminium catalytic system

✍ Masanao Kawabe; Masahide Murata; Kazuo Soga 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 54 KB

The polymerization of 4-methylstyrene with the (trimethyl)pentamethylcyclopentadienyltitanium (Cp\*TiMe 3 )/tris(pentafluorophenyl)borane (B(C 6 F 5 ) 3 )/trioctylaluminium (AlOct 3 ) catalytic system at -20 8C was carried out. The number-average molecular weight (M n ) of the polymers increased lin