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Catalytic Synthesis of Monodisperse Polypropylene Using a Living Polymerization System with a nsa -Fluorenylamidodimethyltitanium-Based Catalyst

✍ Scribed by Cai, Zhengguo; Shigemasa, Mizuki; Nakayama, Yuushou; Shiono, Takeshi


Book ID
120019798
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
32 KB
Volume
39
Category
Article
ISSN
0024-9297

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Catalytic Synthesis of a Monodisperse Ol
✍ Zhengguo Cai; Yuushou Nakayama; Takeshi Shiono πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 121 KB

## Abstract Polymerization of norbornene has been conducted with [__t__‐BuNSiMe~2~(3,6‐__t__‐Bu~2~Flu)]TiMe~2~ (**1**) in toluene at 20 °C using modified methylaluminoxane that contained 0.4 mol‐% of triisobutylaluminium (TIBA) (dMMAO(0.4)) or 1.8 mol‐% of TIBA (dMMAO(1.8)). The **1**‐dMMAO(0.4) ca