Synthesis of Chlorosulfenylphosphorylthio-Substituted Chromium(III) Acetylacetonate and Its Addition to Olefins
β Scribed by O. A. Apanasenko; N. P. Shapkin; A. S. Skobun; I. V. Svistunova
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 26 KB
- Volume
- 75
- Category
- Article
- ISSN
- 1070-3632
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π SIMILAR VOLUMES
Polymer bound olefins undergo free radical initiated 1,2-addition when reacted with a variety of haloalkanes. The strategy could be applied successfully to the solid-phase synthesis of dihaloethenylcyclopropane carboxylic acids which are the key fragments of synthetic pyrethroids.
Scheme 1. The synthesis of phosphine-stabilized silicon(II) hydride 2.
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