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Synthesis of chiral α-amino acids

✍ Scribed by Tushar K Chakraborty; Animesh Ghosh

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
94 KB
Volume
43
Category
Article
ISSN
0040-4039

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## SR)-(-)-N-[1-(Triethoxymethyl)ethylidene]-p-toluenesulfinamide (2) was synthesized from the addition reaction of triethoxyacetonitrile with MeLi followed by (+)-(R)-d-menthyl p-toluenesulfinate (1R). Sulfinimine 2 underwent complete stereoselective reduction with 9-BBN and addition reaction wit